5C: Separation & Purification

1 / 85
Question

If that unknown protein is about , does it run above or below the band?

Tap to flip
Answer

Above; it is larger, so it migrates less far.

Tap to flip back
Question

Why do more volatile compounds elute first in GLC?

Tap to flip
Answer

They stay more in the gas phase and partition weakly into the liquid film.

Tap to flip back
Question

Retention factor

Tap to flip
Answer

Spot distance divided by solvent-front distance; planar chromatography clue: to .

Tap to flip back
Question

Why do large molecules elute first in size-exclusion chromatography?

Tap to flip
Answer

They are excluded from pores and take the shortest path around the beads.

Tap to flip back